Toll Free Helpline (India): 1800 1234 070

Rest of World: +91-9810852116

NAAS RATING: 5.23, Impact Factor: RJIF 5.98 | Free Publication Certificate
updates
NAAS Rating: 5.23 new
Vol. 7, Issue 1 (2018)

Synthesis, characterization and electrochemical studies of symmetrical schiff base complexes of [1-(5 chloro-2-hydroxy-4-methyl- phenyl) ethanone-4-chloro (-3-trifluro methyl) aniline]

Author(s):
Jaishri N Bavane and Rahul B Mohod
Abstract:
Schiff base complexes of Mn(II), Co(II), Ni(II),Cu(II), Zn(II) and Cd(II) synthesized from1-(2-hydroxy-5-methyl-3-nitro phenyl) ethanone and 4-chloro (-3-trifluro methyl) aniline. The ligand and its metal complexes was characterized by elemental analysis, IR, diffuse reflectance spectroscopy. Electrochemical behaviour of these complexes has been studied by cyclic voltammetry. The cyclic voltammograms of the Mn(II)/Co(II)/Cu(II) complexes investigated in DMSO solution exhibit metal centered electro activity in the potential range −1.02 to +0.7V. Electrochemical studies of the complexes reveal that all mononuclear complexes show a one-electron quasi-reversible reduction wave in the cathodic region. The spectral data showed that the ligand behaved as a monobasic bidentate in complexes and was bonded to the metal ions via oxygen atom the azomethine nitrogen atom and the deprotonated phenolic hydroxyl oxygen.
Pages: 149-152  |  830 Views  49 Downloads
How to cite this article:
Jaishri N Bavane, Rahul B Mohod. Synthesis, characterization and electrochemical studies of symmetrical schiff base complexes of [1-(5 chloro-2-hydroxy-4-methyl- phenyl) ethanone-4-chloro (-3-trifluro methyl) aniline]. Pharma Innovation 2018;7(1):149-152.
The Pharma Innovation Journal